WATER TECHNOLOGY MAGAZINE
Swimming pool treatment with UV
From Volume 27, Issue 6 - June 2004
by: David R. Smith
 
 Related Information
  Good chlorine, bad chlorine
  Figure 1
  Figure 2
  Structure of chloramines

Without proper disinfection, swimming pools, wading pools, water parks and water rides can all cause the following symptoms on bathers:

  • burning eyes;
  • itchy skin;
  • swimmer’s ear; and
  • upset stomach.

In the past, the disinfection of choice for pool applications has been chlorine. However, with the use of chlorine, disinfection by-products (DBPs), such as chloramines and trihalomethanes (THMs), lead to the above discomforts for bathers.

To reduce the level of DBPs ultraviolet (UV) light systems are now being used as a supplemental disinfection method to chlorination.

Concerns and effects of chlorine and chloramines

Chlorine disinfection requires additional chemicals and periodic testing to maintain the proper pH balance. But, the addition of chlorine to water lowers the pH of the water.

Chlorine works best within a range of 7.2 to 7.8. Outside this range, the pool bather begins to show skin and/or eye irritation.

As the pH drops with additional chlorine, another chemical, such as soda ash, is added to raise the pH.

Adding more chlorine — again requiring additional chemicals to maintain the desired pH of 7.5 — creates chloramines, which results in further eye irritation and respiratory problems for bathers and gives off the strong chlorine odor common at most indoor pool complexes.

In addition, corrosion to metal components of the pool — ladders, handrail, the building’s heating, ventilation and air conditioning system (HVAC) and other unpainted metal surfaces — is directly caused by chloramines.

UV is the solution

To stop the vicious cycle of adding chemicals, UV is the best solution. UV treatment, in addition to chlorination, will lower the amount of chlorine and other chemicals, while preventing adverse effects on the pH balance of the pool.

Ultraviolet light will not only lower chemical costs, it will also reduce chloramines up to 80 percent, thus eliminating the strong chlorine odor.

Benefits of UV in swimming pools

#1 Lower contaminant levels

One advantage of using UV in a pool application is the level of disinfection it creates against viruses, bacteria, cysts and protozoa.

The disinfection is made without affecting the taste, odor or pH balance in the pool.

Data from the EPA UV Disinfection Guidance Manual (June 2003) shows a 99.99 percent disinfection of Crytosporidium with a dosage of 40 mJ/cm2.

A properly sized UV system will disinfect the entire volume of a pool in six hours or less with a turnover rate at a minimum of four times per day. The turnover rate of four times per day is the minimum requirement for all US states.

The UV system is a constant disinfection source delivering a safe chemical-free barrier against unfound fecal accidents in a fraction of the time required by chlorine.

#2 Removal of chloramines

An additional advantage of using UV light in pool applications is the reduction of chloramines.

The interaction between free chlorine and organic matter forms chloramines (see Good chlorine, bad chlorine, page 56). It is the concentration above 0.2 ppm of chloramines where the chlorine odor and bather symptoms begin.

Ultraviolet light photosynthesizes chloramines, breaking them down into salts, as seen in the following equation:

How well does UV light reduce chloramines?

Claims have been made that UV reduces chloramines up to 85 percent. Such a reduction lessens the chlorine odor and lowers the corrosion rate on the building’s HVAC system, thus reducing maintenance costs.

The UV system allows for the reduction of chlorine use by over 50 percent, cutting chemical costs in half for both chlorine and soda ash for disinfection and pH adjustments.

Increasing the amount of free chlorine may reduce the required disinfection contact time of chlorine.

The time it takes for the results of UV treatment to be seen in a pool with chlorine and chloramines is shown in Figure 1:

Whether ultraviolet light is being produced from a low-pressure/low intensity system, a medium-pressure/high intensity system or a low-pressure/high intensity system, disinfection and reduction of chloramines will occur.

In terms of germicidal effects, the optimum UV range is between 245 and 285 nm (nanometers), which is the heart of the UV-C range (200 to 280 nm).

Different types of UV systems will comparatively have their own advantages and disadvantages.

Placement of a UV system

The placement of the UV system is shown in Figure 2 (see page 58). It is placed after the filters for disinfection of the filtered water and before the chlorine addition to prevent, if any, chlorine destruction.

Sizing a UV system

When sizing an ultraviolet light system start by looking at the following characteristics:

  • Volume of the pool;
  • Turnovers per day;
  • Type of pool; and
  • Required chlorine residual.

The bather load and chloramine levels are other factors to be considered when sizing the UV system. These factors are handled differently depending on the type of UV system being used for the application.

A common dosage range for UV light is 30 mJ/cm2 to 80 mJ/cm2. The low number is used in private pools and other low bather load pools, while the higher dosage systems are used in spas, hot tubs and kiddy pools.

Refernces
  1. Gilkey, David P. DC, Williams, Holly A. DC, Water Disinfection By-Products: Trihalomethanes and Carcinogenicity – Should DCs Care?, www.chiroweb.com/hg, February 1, 2004.
  2. Water Chemistry for Swimming Pools, North Carolina Division of Environmental Health, Department of Environment and Natural Resources, www.deh.enr.state.nc.us/ehs/quality/wph.htm
  3. Surveillance for Waterborne Disease Outbreaks — United States, 1991-1992, CDC MMWR Surveillance Summaries, 11/19/1993 / 42(SS-05);1-22
  4. Pool Treatment 101, Chlorine Chemistry Council, www.c3.org/chlorine_knowledge_center/Pool Treatment101.html
  5. UV Disinfection Guidance Manual Proposal Draft, June 2003, US Environmental Protection Agency (EPA).

David R. Smith, applications sales engineer for Wedeco UV Technologies, Inc., Charlotte, NC, has worked in the water industry for over 15 years. His knowledge of the water industry covers UV, filtration, membrane technology and water chemistry.

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