WATER TECHNOLOGY BULLETIN BOARD
Posted By Nino La villa on 1/29/2010 at 2:10:48 PM
 

I would like to have a recommandation to treat silica from water. We have to treat around 22.7 mg/l of silica.  Is it possible to use standard demineralization resin to remove silica?



Responses:

RE: Silica: Gary Schreiber, CWS VI: 1/29/2010 8:23:34 PM
Silica is removed from water using a Strong Base Anion (SBA) resin in the Hydroxide (OH) form.  Preferable is a Type 1 or Type 1 P SBA resin because you can regenerate it at temperatures higher than 95 degrees F.  A Type 2 cannot be regenerated at higher than 95 F.  The higher temp is needed to remove the silica during regeneration.  So the answer is yes one can use a "standard demineralization resin" to remove silica.

RE: Silica: Laurence D'Alberti: 1/30/2010 11:56:45 PM
I agree with Gary: Sodium silicate can be removed from water with strong base anion exchange resin.  Unfortunately, silicate is very weakly ionic, so it is not slectively removed and resin capacity will be limited in the presence of most other anions.  Removal is complicated by the polymeric forms that often occur.  What is your flow rate in GPM?

RE: Silica: Nino La villa: 2/2/2010 9:09:22 AM
Thank you for your help. Flow rate will be around 8 gpm

RE: Silica: Gary Lindsey: 2/2/2010 5:58:46 PM
MY RESPONSE DOESN'T ADDRESS THE QUESTION DIRECTLY, BUT R.O. COULD ACT AS A STAND ALONE TREATMENT FOR SILICA. OR AS A PRETREATMENT COULD SAVE $ IN RESIN REGENERATION. OF COURSE APPLICATION MIGHT OR MIGHT NOT WARRANT R.O. BOTH FROM A SPACE AND WATER CONSUMPTION STANDPOINT. YOU MIGHT WANT TO DETERMINE  WHAT THE PRODUCT WATER SHOULD BE IN SILICA CONCENTRATION BEFORE CONSIDERING R.O. AS A STAND ALONE TREATMENT. THE REJECTION WOULD BE IN THE 90% RANGE.
 
GARY L. LINDSEY
CWS VI CI

RE: Silica: Ricardo G. Soto: 2/4/2010 11:39:33 AM
No doubt that silica is a problem when you need to remove it.

To select the most suitable water treatment process, we have to know what the alkalinity of the raw water is and the flow rate, plus what is the residual silica level in the product water you can accept.

Silica comes in two forms, one is the colloidal silica, and the other is the ionized (dissolved) or reactive silica.

As I say above, alkalinity is a problem because, and as it "accumulate" in the resin beads, during exhaustion of the resin bed, it "regenerates" the silica, displacing it, downward in the resin bed, to the point where we have an early silica leakage of silica in the product water, followed by a drop in the pH.

I would not recommend RO, because colloidal silica tends to "be filtered" by the RO membrane, so it is necessary to feed a "dispersing agent" to prevent the precipitation on the surface of the RO membrane.

I know there are some RO membrane specially manufactured to support this silica.

We also need what the use of the Silica Free water is.

I would like to receive some comments on my comments.

NA.
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